CompuServe Thread

#Origin of petroleum?

7 messages in this thread
#170510From: Jeff Baldwin/HoustonFeb 25, 1995 8:27 PM
Mike, Ran across this string while catching up on at 20megs of unread messages. Anyone say anything about continued oil accumulations in extant reservoirs? A prof in a Louisiana U. published a theory and supporting data from several old, abandoned fields that are now re-charged with hydrocardons. It seems that resersoir rock which is close enough to source rock can become re-pleted in 10 to 20 yrs. People asked, "Well, if it accumulates that quickly, where does all the excess go once a reservoir is full? It seems that shales are not as impermeable as once thought. There is a distinct halo of hydrocarbons around and above a reservoir. The halo forms a "chimney". Hydrocarbons leak off at an astounding rate. Ergo, much of the unrefined "oil spill" material in (for example) the world's oceans that can not be traced to a spill is indeed from natural sources. As for the organic source of hydrocarbons, I routinely estimate financial recoverables from source rock via remote sensing (using electric, nuclear, and acoustic signal sources) of in situ rock and rock-fluid's physical characteristics. I have been on site for recovery of source rock material and have been involved of recovery of formation material which is in the process of out-gassing and seeping oil (it is called "pop") as it is inspected at the surface. Advanced technologies are available for measuring pop and gasssing of rock. I have held the organic material in my hand and watched it pop and spit. The samples have been from 5,000feet to 22,500feet subsurface. The technologies are called mudlogging, wireline logging, and petrophysical core measurments. My company provides advanced neural network and fuzzy logic hybrid systems for evaluation of the economic potential of (among other items) organic source rock. Paleontologists (we call them bug counters) look at the organic material and classify and date the material. What I am saying is that there exists an entire scientific industry engaged in identifying and measuring the physical maturity of organic source rock for the purpose of estimating the worth of a reservoir. It *has* to make money. Wells currently cost $0.5million to $15+million to drill and complete. On average, only one in eight (1/8) wells are a success. Thus, if there was "nothing to" the idea that organic source rock yeilds oil, or if there was another and better (more correct) explanation for the origins of hydrocarbons, then I would venture to guess that there would be kazillions of bucks thrown at the problem of identifying and understanding that xxx source of hydrocarbons. If any of this was already covered, I am sorry for repeating. -JB
#170993From: Mike FayFeb 28, 1995 12:18 PM
Hi Jeff! Many thanks for your most informative post!! >> As for the organic source of hydrocarbons, I routinely estimate financial recoverables from source rock via remote sensing (using electric, nuclear, and acoustic signal sources) of in situ rock and rock-fluid's physical characteristics. << Would that be the new ACME pocket nuke demo charge? Or do you wait for a holocaust?? <VBG – seriously, how do you use nuclear sensing??> >> … It *has* to make money. Wells currently cost $0.5million to $15+million to drill and complete. On average, only one in eight (1/8) wells are a success. Thus, if there was "nothing to" the idea that organic source rock yeilds oil, or if there was another and better (more correct) explanation for the origins of hydrocarbons, then I would venture to guess that there would be kazillions of bucks thrown at the problem of identifying and understanding that xxx source of hydrocarbons. << This is clearly convincing that it is a "given" in the industry. But are you able to supply any more details on just how they are known, and/or work on the assumption, that it is organic in origin. Did you snag any of the earlier posts on this thread? (They're probably gone by now.) Basically asking for more precise details of how they came to that conclusion and how they rule out some potential confounders. All from an armchair perspective — I am not trying to argue the earth is flat, I'm just trying to see to what level petrol being from organic origins is "proven" by letting the findings and, the theories they generate, speak for themselves. Is any of this making sense. It is of course important in the abstract to say that's the working assumption of everyone in the business. But it doesn't actually fill in the blanks of why. And I'm not sure you can; we may in fact be best served by one of the bug counters, if one were to show up around here. Thanks!! – Mike
#171035From: Jeff Baldwin/HoustonFeb 28, 1995 4:36 PM
>>Did you snag any of the earlier posts on this thread?<< Nope. Sorry if I repeat. >>more precise details of how they came to that conclusion and how they rule out some potential confounders.<< Every organic "ooz" has a chemical "fingerprint" comprised of ratios of atoms which are found in various organic materials, and ratios of molecules of different types. What plants and animals were present during deposition, what fluids present, atmostpheric conditions, etc., all go into making the fingerprint. There is a further fingerprint as a result of what is called diagenesis, or chemical changes to the rocks after burial. Geochemistry is a well grounded and mature science. The rocks and fluids all interact during diagenesis in ways that are controlled by geochemical processes and understandable via that science. Everything is predictable. You got the original stuff, you got the energy and forces applied as a function of time, you got the washing action of subsurface migratory fluids …. add 'em all up in your organic chemistry equation and *presto* you have only one possible fingerprint of oils that can be "cracked" from the source rock. Lo *AND* behold, you look around near the organic source rock and *there it is*!! Some oil (or gas) with just the right fingerprint for it to have come from that particular source rock. Other possible sources? Nope. There are too many coincidental trace atoms (primarily vanadium and gadolinium, but others exist) that have nothing to do with oil, per se, in both the source and the product of that source. There can be no other source from which the observed mix of molecules in thier respective fingerprint encarnations could have been cooked up. Add to that the new papers published by a Louisiana U. Prof showing the re-charging of known, depleted reservoirs close to source rock, where the fingerprint of the source rock matches the fingerprint of the oils produced in the reservoirs up to initial depletion and now matches the oils produced today after recharging. Any other explanation for the source of the oils besides the most available one (the organic source rock) must thus be discarded as being overly "energetic" in its untold and most probably dubious mechanisms. >>how do you use nuclear sensing??<< Chemical and electrical sources attached to metal tubes (2 to 5 inches in diameter) filled with computer equipment, sealed against 20,000+psi pressure and 350 deg f temperature are lowered on miles-long cables down drilled holes (8 to 12 inches diameter). Chemical sources produce moderate energy (ca. 3 Mev) neutrons and gamma rays that leave the tool, bang around in the formation, and finally return to the tool detectors for measurement (energy, time, numbers). The measured signals are encoded and sent up the cable for recording and processing at the surface, or transmission via satellite to the "home" office for perusal and processing. Electrical sources use deuterium and tritium (charged particles) in high voltage, staged electrical discharge-like ramps to crash these atoms together and cause high energy (14 Mev) neutron production. The neutrons interact with tool, borehole, and formation materials, slowing down to thermal levels. They are then absordbed by various materials and produce gamma ray radiation time and energy spectra. From all of these measurments it is possible to compute elemental abundances of hdyrogen, carbon, oxygen, calcium, gadolinium, etc., void space in rocks (holes in which the oil and gas exit), mineral types and abundances, fluid types and abundances, fluid flow characteristics, and rock mechanical properties (these last two require electrical and acoustic measurments to really be performed properly). The radioactive sources used are extremely dangerous if you were to hold them in your hand, but proper shielding and operating proceedure reduces risk to very small indeed. Companies like the electrical sources better because if an accident occurrs and you loose a source in the hole or stick a tool in the hole then all you have to do to render the source inactive is pull the cable off the tool at what is called the weak-point (a specially designed connection which allows the engineer to break the link between tool and cable should the need arise. Don't worry about the chemical sources ….. there are extreme saftey measures required by the government to control and monitor source loss and recovery operations. It doesn't happen often, but when it does there are enough saftey proceedures and container-strength requirements that there has never been any real problem in all the years of use ….. and in the overall scheme of things, the sources may be dangerous to a person's hand, but the amounts of material in any one tool is pretty small. Even so, the government acts like its a 3 Mile Island when talking about this type of stuff. And I guess it is a good idea, really, because by over reacting they ensure that not one atom of unwanted material ever has a chance of harming anyone. So these technologies are quite useful and extremely safe. After a measurement is produced and evaluated, the data is merged with data from acoustic recodings of explosions set off on the surface (siesmic cross-sections or lines). The size of the reservoirs is able to be deduced from processing of many such lines. Also, the physcial properties of the rocks and fluids in those reservoirs can be estimated based upon many well measurement records, called logs, together with those lines. This is how you tell not only where any oil/gas might be in a well you just drilled, but you also can predict the economics of recovery based upon these measurments (nuclear and otherwise). Is that more than you ever wanted to know about petrophysical well logging and data processing?
#171053From: Ed Fisher/PAFeb 28, 1995 6:41 PM
<<fingerprint of the source rock matches the fingerprint of the oils produced in the reservoirs up to initial depletion and now matches the oils produced today after recharging.>> Interesting thread, Jeff! The above statement, particularly, is something I hadn't run across before. It is interesting that a formation will recharge in a time scale that we can measure. How substantial is this recharging? My very basic, 15 year old geology training made me believe that these oil-bearing deposits were ancient and "fermented to completion" if you will, and once they were pumped dry and maybe flushed once or twice to catch the crude that didn't come to the surface the first time, they were empty. Can you in fact go so far as to identify a formation that is aching to produce oil or gas but has not yet done so; or to go a step further, look at a producing formation and say, "Hmm, this may produce even better later on" or "This one will recharge and this one won't"…? Regards, ed
#171141From: Jeff Baldwin/HoustonFeb 28, 1995 11:42 PM
>>My very basic, 15 year old geology training made me believe that these oil-bearing deposits were ancient and "fermented to completion" if you will, and once they were pumped dry and maybe flushed once or twice to catch the crude that didn't come to the surface the first time, they were empty.<< Me, too. That's what caught my eye about the abstract I read. I am trying to locate the author and publication. I have a viedo someone lent me of one of the 3D reservoir fluid flow models generated either by that same prof or at that same converence. Very spiffy stuff!! >>How substantial is this recharging?<< I asked the same question, but not in quite this nice a fashion. My tone was … how shall we say, somewhat derisive. Perhaps jeering. It seems that the charging is complete under the right conditions and can be accomplished in as few as about 20 years. >>Can you in fact go so far as to identify a formation that is aching to produce oil or gas but has not yet done so; or to go a step further, look at a producing formation and say, "Hmm, this may produce even better later on" or "This one will recharge and this one won't"…?<< Apparently so. I'm sure the model will be hotly debated, but the fact that there's new oil in some of them thar Louisiana fields is undeniable …. especially when someone is trucking the monetary gains from production in these "depleted" fields to the bank. -JB
#171149From: Ed Fisher/PAMar 1, 1995 12:43 AM
<<That's what caught my eye about the abstract I read. I am trying to locate the author and publication. I have a viedo someone lent me of one of the 3D reservoir fluid flow models generated either by that same prof or at that same converence. Very spiffy stuff!!>> Lemme know. This is new and interesting.
#171157From: Jeff Baldwin/HoustonMar 1, 1995 1:56 AM
Ed, >>Lemme know.<< show nuf', podna!